Through vintage film clips of past Bond movie epics, and with the participation of several former "Bond Girls" as interviewees (among them Dr. No's Ursula Andress and Diamonds Are Forever's Jill St. John), the documentary traces the evolution of the typical James Bond heroine from decorative damsel in distress to gutsy (but still decorative) participant in the action.

Set in the 1900s, when the British Secret Service was a new, unofficial arm of military activity, the series features Captain Robert Virgin - an officer and a gentleman who fights as a man of honour. Armed only with intelligence, ingenuity, physical strength and abundant charm, Virgin faces every sort of peril as he defends King and country - from industrial espionage to anarchist bomb plots, assassination attempts to kidnapping.

The evil crime syndicate Thanatos is bent on taking over the world, using a magnetic wave generator that will cause all metal-based machinery to grind to a halt. However, the well-known British secret agent normally assigned to such tasks isn't available, so they engage his civilian brother, Neil, to help. Neil, played by Neil Connery, is a world-class plastic surgeon, hypnotist, and lip-reader, which turn out to be precisely the skills required for thwarting Thanatos.