After his girlfriend's tragic death, devastated stand-up comic Zoe Hardwick drops his budding career on stage and moves back home. But when his father, the principal of an elementary school, lands him a gig teaching kindergarten, Zoe finds himself standing before a very different demographic.

Wife and mother Valerie Plame has a double life as a CIA operative, hiding her vocation from family and friends. Her husband, Joseph Wilson, writes a controversial article in The New York Times, refuting stories about the sale of enriched uranium to Iraq, Then Valerie's secret work and identity is leaked to the press. With her cover blown and other people endangered, Valerie's career and personal life begin to unravel.

In exchange for his freedom, charming con artist Neal Caffrey provides his expertise to help straight-man FBI agent Peter Burke catch elusive white-collar criminals.